| Paraguay Open U21 Women | 2019/09/12 20:15 | Maki Shiomi v Valentina Rios | L | 3-0 |
| Paraguay Open Women | 2019/09/11 19:40 | Ana Codina v Valentina Rios | L | 3-0 |
| Paraguay Open U21 Women | 2019/09/11 15:55 | Panambi Caceres v Valentina Rios | W | 1-3 |
| Paraguay Open Women | 2019/09/10 19:40 | Valentina Rios v Cielo Mutti | W | 3-0 |
| Paraguay Open U21 Women | 2019/09/10 15:10 | Bruna Takahashi v Valentina Rios | L | 3-0 |
| Central American Championships Women | 2019/05/31 00:30 | Paula Medina v Valentina Rios | L | 4-1 |
| Qatar Open - GD | 2017/04/28 19:00 | Valentina Rios v Carolina Cardenas | W | 3-0 |